The course aims at providing the necessary background for the interpretation of chemical phenomena, for the understanding of the structure and properties of molecules and crystalline solids, and the comprehension and…
Scheda dell'insegnamento
Obiettivi formativi
The course aims at providing the necessary background for the interpretation of chemical phenomena, for the understanding of the structure and properties of molecules and crystalline solids, and the comprehension and handling of energetic phenomena concerning chemical and electrochemical systems.
Programma
The course aims to provide the basic knowledge necessary for the interpretation of chemical phenomena, for the understanding of the structure and properties of crystalline solids and for the understanding and calculation of energy phenomena related to chemical and electrochemical systems.
ATOM Constitution of the nucleus, structure of the hydrogen atom and atomic models (Bohr and quantum-mechanical) Quantum numbers, exclusion principle and Hundt rule Spatial form of s,p and d orbitals CLASSIFICATION OF THE ELEMENTS AND PERIODIC TABLE Electronic configuration of the elements and periodicity in the chemical and physical properties Atomic radius, ionization energy and electron affinity Subdivision into metals, non-metals and semimetals. Basics on the main groups of the periodic table and some transition metals. THE CHEMICAL BOND Bond: ionic, covalent, metallic. Intermolecular interactions. Covalent bond: single, double and triple. Molecular geometry, hybridisation and resonance. Notes on the theory of molecular orbitals. NOMENCLATURE, FORMULAS AND STOICHIOMETRY Atomic and molecular mass, the mole, Avogadro's constant. Acid-base reactions and formation of salts. Oxidation state and balancing of redox reactions. Mass relationships in a chemical reaction, limiting reagent. Combustion reactions GASEOUS STATE Ideal gas laws. State equation of ideal gases. Equilibrium distribution of kinetic energies in an ideal gas (Boltzmann). Liquefaction of a gas. LIQUID STATE Vapour pressure of pure liquids. Solutions: ways to express concentration. Dissociation and ionization degree. Colligate properties of solutions, both electrolytic and non. Definition of acid and base according to Arrhenius, Brønsted and Lewis. Ostwald dilution law. Ionic product of water, pH and pOH. SOLID STATE Unit cell and structure of simplestcrystalline solids. Crystal lattices. Classification of solids. CHEMICAL KINETICS AND CATALYSIS Reaction rate and order. Arrhenius equation. Activation energy. Catalysis and catalysts. CHEMICAL EQUILIBRIUM Mass action law. Equilibrium constant. Homogeneous and heterogeneous chemical equilibria. Le Chatelier principle and influence of the temperature on the equilibrium. CHEMICAL THERMODYNAMICS First, second and third Principle. Reaction enthalpy and Hess law. Change in entropy and free energy of a reaction. Spontaneity criterion. ELECTROCHEMISTRY Normal and effective potential of an electrode. Electrochemical cells and Nernst equation. Electrochemical force of a cell. Reactivity of metals with ocids, oxidizing or not. Electrolysis and Faraday laws. ORGANIC CHEMISTRY Nomenclature and properties of the main organic compounds. Most common functional groups and their main reactions. Isomerism: structural, geometric, conformational.
Modalità d'esame
E' possibile sostenere l?esame in anticipo rispetto all?acquisizione della frequenza
Testi di riferimento
PRINCIPLES OF GENERAL CHEMISTRY (International Edition). Author: Martin Silberberg. Publisher: MgGraw-Hill
Codice insegnamento 06KWRWN