Domande d'esame VERIFICATO

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Complex and simple lipids, main classes of hydrolysable lipids, hydrolysis reactions with mechanism.
Fatty acids: functional groups and reactivity.
Structure of triglycerides: functional groups and reactivity, comments on biodiesel preparation methods.
Absolute and relative configuration, drawing and assigning stereochemistry to D-alanine and S-serine.
Reducing and non-reducing sugars: formation of glycosides.
Anomers of monosaccharides, definition and discussion of mutarotation in glucose.
α and β-glycosidic linkages in polysaccharides: drawing and comparing structures of amylose and cellulose.
Amino acids with examples of secondary alcohol, amide, thiol, sulfide, phenol, side chain primary ammonium, side chain carboxylate, secondary amine.
Nitrogen protecting groups in peptide synthesis: main protecting reactions (with mechanism).
Carboxylic acid protecting groups in peptide synthesis: main protecting reactions (with mechanism).
Protecting groups: orthogonal and modulated liability strategies with examples.
Molar concentration calculation of a molecule dissolved in water using UV absorbance data.
Description of the 1H-NMR spectrum of cinnamic acid, assigning all resonances considering chemical shift, multiplicity (with diagram), and integral.

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